To make commission on bookings, always check that you've got one of your affiliate IDs in the URL.
Your affiliate URL is the following: https://www.booking.com/?aid=xxxxx. The Affiliate ID has to be present in the URL while the reservation is being made in order to earn commission.
Once you are in the reservation process, you have the option of paying in advance by choosing a non-refundable rate. With this type of rate, the credit card you've provided will be charged in advance. In this way, you will be able to use your corporate credit card.
In order to charge the 3rd party credit card (as the credit card belongs to you, not to the customer), the accommodation administration might need additional information. You might be asked to submit the credit card authorization form.
Please check with the accommodation directly or our Customer Service whether the credit card authorization form is needed.
Contact details of the property are always mentioned in the reservation confirmation.
Customer Service contacts can be found here: https://www.booking.com/content/offices.en-gb.html The office is open 24/7 and will be happy to assist you.